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CsCl crystallizes in a unit cell that contains a Cs+ ion at the center of a cube and a Cl- ion at each corner. The unit cell of CsCl is .


A) amorphous
B) primitive cubic
C) close packed
D) body- centered cubic
E) face- centered cubic

F) B) and C)
G) A) and C)

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B

Hydrogen bonding is a special case of _ .


A) ion- dipole attraction
B) London- dispersion forces
C) dipole- dipole attractions
D) none of the above
E) ion- ion interactions

F) B) and E)
G) B) and D)

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Which one of the following substances will not have hydrogen bonding as one of its intermolecular forces?


A)
Which one of the following substances will not have hydrogen bonding as one of its intermolecular forces? A)    B)    C)    D)    E)
B)
Which one of the following substances will not have hydrogen bonding as one of its intermolecular forces? A)    B)    C)    D)    E)
C) Which one of the following substances will not have hydrogen bonding as one of its intermolecular forces? A)    B)    C)    D)    E)
D)
Which one of the following substances will not have hydrogen bonding as one of its intermolecular forces? A)    B)    C)    D)    E)
E) Which one of the following substances will not have hydrogen bonding as one of its intermolecular forces? A)    B)    C)    D)    E)

F) B) and E)
G) C) and E)

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The predominant intermolecular force in (CH3) 2NH is .


A) hydrogen bonding
B) ion- dipole forces
C) ionic bonding
D) London dispersion forces
E) dipole- dipole forces

F) B) and C)
G) A) and D)

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A

Which of the following is not a type of solid? ionic Molecular supercritical metallic Covalent- network


A) molecular
B) metallic
C) supercritical
D) covalent- network
E) ionic

F) A) and B)
G) C) and D)

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The phase changes B -C and D -E are not associated with temperature increases because the heat energy is used up to .


A) rearrange atoms within molecules
B) break intramolecular bonds
C) increase distances between molecules
D) increase the density of the sample
E) increase the velocity of molecules

F) B) and D)
G) C) and D)

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Metallic solids do not exhibit .


A) extreme brittleness
B) variable hardness
C) excellent thermal conductivity
D) variable melting point
E) excellent electrical conductivity

F) C) and D)
G) B) and C)

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The substance with the largest heat of vaporization is _ . I2 Br2 Cl2 F2 O2


A) O2
B) Cl2
C) I2
D) F2
E) Br2

F) A) and B)
G) All of the above

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Based on the figure above, the boiling point of ethyl alcohol under an external pressure of 0.0724 atm is °C.


A) 60
B) 80
C) 40
D) 70
E) 20

F) C) and D)
G) A) and B)

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Chromium crystallizes in a body- centered cubic unit cell. There are chromium atoms per unit cell.

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Large intermolecular forces in a substance are manifested by .


A) high critical temperatures and pressures
B) high heats of fusion and vaporization
C) high boiling point
D) low vapor pressure
E) all of the above

F) A) and C)
G) None of the above

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Which of the following molecules has hydrogen bonding as its only intermolecular force?


A) HF
B) H2O
C) C5H11OH
D) C6H13NH2
E) None, all of the above exhibit dispersion forces.

F) A) and B)
G) None of the above

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The property responsible for the "beading up" of water is .


A) surface tension
B) hydrogen bonding
C) vapor pressure
D) density
E) viscosity

F) D) and E)
G) None of the above

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Of the following, should have the highest critical temperature.


A) CCl4
B) CF4
C) H2
D) CBr4
E) CH4

F) C) and D)
G) A) and E)

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The unit cell with all sides the same length and all angles equal to 90° that has lattice points only at the corners is called .


A) primitive cubic
B) spherical cubic
C) face- centered cubic
D) monoclinic
E) body- centered cubic

F) B) and E)
G) C) and D)

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A

In which of the following molecules is hydrogen bonding likely to be the most significant component of the total intermolecular forces?


A) C5H11OH
B) CO2
C) CH3OH
D) CH4
E) C6H13NH2

F) A) and B)
G) A) and C)

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A volatile liquid is one that .


A) is highly viscous
B) readily evaporates
C) is highly flammable
D) is highly cohesive
E) is highly hydrogen- bonded

F) A) and B)
G) A) and C)

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Elemental iodine (I2) is a solid at room temperature. What is the major attractive force that exists among different I2 molecules in the solid?


A) dipole- dipole attractions
B) covalent- ionic interactions
C) London dispersion forces
D) dipole- dipole rejections
E) ionic- dipole interactions

F) A) and C)
G) A) and D)

Correct Answer

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Of the following substances, only has London dispersion forces as the only intermolecular force. Of the following substances, only has London dispersion forces as the only intermolecular force.   A)  Kr B)  HCl C)  CH<sub>3</sub>OH D)  H<sub>2</sub>S E)  NH<sub>3</sub>


A) Kr
B) HCl
C) CH3OH
D) H2S
E) NH3

F) B) and E)
G) B) and D)

Correct Answer

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The phase diagram of a substance is given above. The region that corresponds to the solid phase is


A) w
B) x
C) y
D) z
E) x and y

F) A) and B)
G) A) and C)

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